I agree with bigjimb, oregon isn't an external grade of timber. I've used it as jin poles etc and it has it's uses but it wouldn't be high on my list for boat skids. The stuff we used was Canadian Skookum.
You've bought kd. Think of it as 'pre shrunk' - it is for use where seasoning and the associated shrinking has been achieved prior to the member being used in internal construction. As you dunk it under water the beams are going to want to reconstitute somewhat. The effects won't be catastrophic, but I'd certainly be giving a little extra clearance on bolt holes etc to give it the chance to do what it will do naturally, without splitting too much.
I'd also entertain strapping or binding the ends to prevent splitting.
C.N. oil is as good a rot preventer as any and I'd be liberal with it. You can get it from the hardware. K.D. generally is raw and not treated with anything.
I personally probably would just go for some slightly larger section cca rougher header.
Tony and the boys at Moxon's have some amazing timbers, but I don't know that I'd bother them (or my bank account) for burmese teak or King billy pine to 'waste' on a boat trailer?